During the Daily Scrum, each Development Team member typically answers three key questions: 'What work am I going to do today?' to plan activities for the next 24 hours, 'What impediments are in the way of my accomplishing my work?' to identify any barriers to progress, and 'What work did I do yesterday?' to share accomplishments and completed tasks from the previous day. These questions help ensure the team stays coordinated and address any challenges promptly.